(a)
The orbital speed of a hydrogen atom is given as,
v 1 = e 2 n×4π ε 0 ( h 2π ) (1)
where, permittivity of free space is ε 0 , charge on an electron is e, plank’s constant is h, and mass of electron is m.
For level n=1,
Substitute the values in the above equation.
v 1 = ( 1.6× 10 −19 ) 2 2×8.85× 10 −12 ×6.62× 10 −34 =0.0218× 10 8 =2.18× 10 6 m/s
For level n=2,
v 2 = ( 1.6× 10 −19 ) 2 2×2×8.85× 10 −12 ×6.62× 10 −34 =1.09× 10 6 m/s
For level n=3,
v 3 = ( 1.6× 10 −19 ) 2 3×2×8.85× 10 −12 ×6.62× 10 −34 =7.27× 10 5 m/s
Thus, the orbital speed of electron in hydrogen atom in first, second and third level is, 2.18× 10 6 m/s, 1.09× 10 6 m/sand 7.27× 10 5 m/s.
(b)
The orbital period of electron at level n is given as,
T n = 2π v n × n 2 h 2 ε 0 πm e 2
For level n=1,
T 1 = 2π 2.18× 10 6 × ( 6.62× 10 −34 ) 2 ×8.85× 10 −12 π×9.1× 10 −31 × ( 1.6× 10 −19 ) 2 =1.527× 10 −16 s
For level n=2,
T 2 = 2π v 2 × ( 2 ) 2 h 2 ε 0 πm e 2 = 2π 1.09× 10 6 × ( 6.62× 10 −34 ) 2 ×8.85× 10 −12 π×9.1× 10 −31 × ( 1.6× 10 −19 ) 2 =1.22× 10 −15 s
For level n=3,
T 3 = 2π v 3 × ( 3 ) 2 h 2 ε 0 πm e 2 = 2π 7.27× 10 5 × ( 6.62× 10 −34 ) 2 ×8.85× 10 −12 π×9.1× 10 −31 × ( 1.6× 10 −19 ) 2 =4.11× 10 −15
Thus, the orbital speed of each these levels is 1.527× 10 −16 s, 1.22× 10 −15 sand 4.11× 10 −15 srespectively.