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Question

A vertical cyclinder with heat - conducting with heat conducting walls is closed at the bottom and its fitted with a smooth light piston. It contains one mole of an ideal gas. The temperature of the gas is always equal to the surrounding's temperature To . The piston is moved up slowly to increase the volume of the gas to n times. Which of the following is incorrect?

A
Work done by the gas in RToln(n).
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B
Work done against the atmosphere is RTo(n1).
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C
There is no change in the internal energy of the gas.
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D
The final presure of the gas is 1n1 times its initial pressure.
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Solution

The correct option is C The final presure of the gas is 1n1 times its initial pressure.
Work Done by gas (isothermal process) :
W=nRTln(V2V1)=RToln(n)
Work Done against Atmosphere (Pressure of atmosphere is constant P & Volume is decreased):
W=PV=P(nVV)=PV(n1)=RTo(n1)
As there is no change in temperature hence no change is Internal Energy (Always in synchronization with atmosphere).
Ideal Gas Equation:
PV=nRTPV=RToP(nV)=RToP=Pn

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