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Question

A vertical cylinder with heat-conducting wall is closed at the bottom and is filled with a smooth light piston. It contain one mole of an ideal gas. The temperature of the gas is always equal to the surrounding;s temperature To. The piston is moved up slowly to increase the volume of the gas to η timers. Which of the following is incorrect?

A
Work done by the gas is RTo in η.
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B
Work done against the atmosphere is RTo(η1)
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C
There is no change in the internal energy of the gas.
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D
The final pressure of the gas is 1(η1) times its initial pressure.
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Solution

The correct option is D The final pressure of the gas is 1(η1) times its initial pressure.
Work Done by gas (isothermal process) :
W=nRTV2V1=RT0ln(n)

Work Done against Atmosphere (Pressure of atmosphere is constant P & Volume is decreased):
W=PΔV=P(nVV)=PV(n1)=RT0(n1)

As there is no change in temperature hence no change is Internal Energy (Always in synchronization with atmosphere).
Ideal Gas Equation:

PV=PV
P(nV)=PV

P=Pn

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