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Question

A vertical hollow cylinder of height 1.52 m is fitted with a movable thickness. The lower half of the cylinder contains an ideal gas and the upper half is filled with that of mercury. The cylinder is initially at 300 K. When the temperature is raised, half of the mercury comes out of the cylinder. Find the temperature assuming the thermal expansion of mercury to becomes negligible.

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Solution

At initial stage:
Pressure of gas = Pressure of Hg + Pressure of atmospheric air =76+76=152cm

T=300k
V=V1/2
where, V1 is volume of cylinder.

At final state after heating:
Pressure of gas = Pressure of Hg + Pressure of atmospheric air =38+76=114cm

V=3V14
Applying gas equation, we have

152×V12×300=144×(3V1/4)T

=337.5k

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