A vessel contains air at a temperature of 150C and 60% R.H. What will be the R.H if it is heated to 200C? (S.V.P at 150C is 12.67 & at 200C is 17.36mm of Hg respectively)
A
262%
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B
26.2%
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C
44.5%
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D
46.2%
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Solution
The correct option is C 44.5% By definition, V.PS.V.P×100 =60100(both VP and SVP are in room temperature) =(V.P)1512.67 (V.P)15=7.6mmofHg Now since unsaturated vapour obeys gas equation & mass of water remains constant so P = (nRTV) ⇒PαT (V.P)15(V.P)20 =273+15273+20 ⇒(RH)20= 7.73 mm of Hg So (R.H)20=(V.P)20(S.V.P)20×100 =44.5%