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Question

A vessel is filled with an ideal gas at a pressure of 10 atm and temperature 27C. Half of the mass is removed from the vessel and temperature of the remaining gas is increased to 87C. Then the pressure of the gas in the vessel will be:

A
5 atm
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B
6 atm
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C
7 atm
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D
8 atm
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Solution

The correct option is C 6 atm
Given : Initial temperature of the gas Ti=27oC=300K
Initial pressure of the gas Pi=10 atm
Final temperature of the gas Tf=87oC=360K
Final mole of gas in the vessel nf=ni2
Using ideal gas equation, PV=nRT

Initially, 10V=niR(300) ..........(1)
Let the final pressure in the vessel be Pf.
Finally, PfV=ni2R(360) ...........(2)
Dividing (1) and (2), we get Pf10=3602×300 Pf=6 atm

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