A vessel is filled with an ideal gas at a pressure of 10 atm and temperature 27∘C. Half of the mass is removed from the vessel and temperature of the remaining gas is increased to 87∘C. Then the pressure of the gas in the vessel will be:
A
5 atm
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B
6 atm
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C
7 atm
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D
8 atm
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Solution
The correct option is C6 atm Given : Initial temperature of the gas Ti=27oC=300K
Initial pressure of the gas Pi=10 atm
Final temperature of the gas Tf=87oC=360K
Final mole of gas in the vessel nf=ni2
Using ideal gas equation, PV=nRT
Initially, 10V=niR(300) ..........(1)
Let the final pressure in the vessel be Pf.
Finally, PfV=ni2R(360) ...........(2)
Dividing (1) and (2), we get Pf10=3602×300⟹Pf=6 atm