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Question

A welding fuel gas combines carbon and Hydrogen only. On burning it gives 3.38g of CO2 and 0.690g of water and no other products. A volume of 10L (STP) of this gas found to weigh 11.6g. Calculate empirical formula.

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Solution

(i) Empirical formula

1 mole of CO2 contains 12 g of carbon

Therefore, 3.38 g of CO2 will contain carbon

= 12g44g×3.38g

= 0.9217 g

18 g of water contains 2 g of hydrogen

Therefore, 0.690 g of water will contain hydrogen

= 2g18g×0.690

= 0.0767 g

As hydrogen and carbon are the only elements of the compound. Now, the total mass is:

= 0.9217 g + 0.0767 g

= 0.9984 g

Therefore, % of C in the compound

= 0.9217g0.9984g×100

= 92.32 %

% of H in the compound

= 0.0767g0.9984g×100

= 7.68 %

Moles of C in the compound,

= 92.3212.00

= 7.69

Moles of H in the compound,

= 7.681

= 7.68

Therefore, the ratio of carbon to hydrogen is,

7.69: 7.68

1: 1

Therefore, the empirical formula is CH.


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