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Question

a) What do you mean by amonolysis of alkyl halides give chemical reaction?
b) Write that reaction which is used for following.
i) Ascent of amine series.
ii) To synthesis amine containing one carbon less than that of in the amide.

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Solution

a) Amonolysis of alkyl halides:
Alkyl halides react with ammonia to form amine and hydrogen halide.
CH3Cl+NH3CH3NH2+HCl
b) i) Ascent of amine series.
CH3CH2NH2+NOClCH3CH2Cl+N2+H2O
CH3CH2Cl+NaCNCH3CH2CN+NaCl
CH3CH2CN+4HLiAlH4−−−CH3CH2CH2NH2
ii) To synthesis amine containing one carbon less than that of in the amide.
CH3CONH2Br2/KOH−−−−−CH3NH2

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