Salt is a compound formed when a metal replaces the hydrogen atom in an acid. The names and formulae of two salts are sodium chloride, NaCl, and ammonium chloride, NH4Cl, respectively. Sodium chloride salt (NaCl) is formed from an acid, hydrochloric acid (HCl), and a base (NaOH). Ammonium chloride (NH4Cl) is formed from an acid, hydrochloric acid (HCl), and a base, ammonium hydroxide (NH4OH).
Salts having the same positive ions or the same negative ions belong to one family of salts. For example, calcium chloride (CaCl2) and calcium sulphate (CaSO4) belong to the same family of salts called ‘calcium salts’ because they both contain the same positively charged ions, calcium ions (Ca2+). Similarly, zinc sulphate (ZnSO4) and copper sulphate (CuSO4) belong to the same family of salts called ‘sulphate salts’ because they both contain the same negatively charged ions, sulphate ions (SO42-).
Salts that contain water of crystallisation are called ‘hydrated salts’. For example, copper sulphate crystals contain five molecules of water of crystallisation in one formula unit and hence is written as CuSO4.5H2O. It is also called copper sulphate pentahydrate.
Salts that have lost their water of crystallisation on heating are called ‘anhydrous salts’. For example, when copper sulphate crystals (CuSO4.5H2O), which are blue, are heated strongly, they lose all the water of crystallisation and form anhydrous copper sulphate (CuSO4), which is white.
Hydrated salts:
Copper sulphate pentahydrate crystals, CuSO4.5H2O, are blue.
Iron sulphate heptahydrate crystals, FeSO4.7H2O, are green.
Blue litmus turns red. NH4Cl is formed from a weak base, ammonium hydroxide (NH4OH), and a strong acid, hydrochloric acid (HCl). So, on dissolving in water, NH4Cl will hydrolyse to form more H+ ions than OH- ions, and thus it is acidic.