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Question

(a) What is the difference between a cation and an anion ? Explain with examples.
(b) The valencies (or charges) of some of the ions are given below :
Ion Valency (Charge) Ion Valency (Charge)
Sodium ion 1+ Nitrate ion 1–
Copper ion 2+ Sulphide ion 2–

Using this information, write down the formulae of :
(i) Sodium sulphide
(ii) Copper nitrate

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Solution

Cation Anion
1. Cation is a positively charged ion. 1. Anion is a negatively charged ion.
2. When a neutral atom loses one or more electrons, it develops an overall positive charge and becomes a cation. 2. When a neutral atom gains one or more electrons, it develops an overall negative charge and becomes an anion.
3. A cation has fewer electrons than the neutral (normal) atom of that element. 3. An anion has more electrons than the neutral (normal) atom of that element.
4. Example: Sodium atom readily loses an electron to form a positively charged sodium ion.
Na → Na+ + e
4. Example: Chlorine atom accepts an electron to become a negatively charged chloride ion.
Cl + e → Cl
Similarly, calcium atom loses two electrons to become a positively charged calcium ion. Thus, the cation formed has two units of positive charge.
Ca → Ca2++ 2e
Oxygen atom readily accepts two electrons to become a negatively charged oxygen ion. Thus, the oxygen anion formed has two units of negative charge.
O + 2e− → O2

(b) Formula of the listed compounds can be derived by crossing the individual valencies over the ions/elements. Therefore, the formula for sodium sulphide and copper nitrate are:
(i) Na2S
(ii) Cu(NO3)2

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