(a) SO2 is acidic in nature. When it is dissolved in water, sulphurous acid is formed.
Chemical equation: SO2(g) + H2O(l) H2SO3(aq)
(b) Na2O is basic in nature. When it is dissolved in water, sodium hydroxide is formed.
Chemical equation: Na2O(s) + H2O(l) 2NaOH(aq)