Distinguishing Test of Terminal and Non Terminal Alkynes
A R - C ≡ C -...
Question
ALindlar′s←−−−−−CatalystR−C≡C−RBirch reduction⟶B
Where, A and B are geometrical isomers (R−CH=CH−R).
Choose the correct option from the following:
A
A is trans, B is cis
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B
A and B both are cis
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C
A and B both are trans
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D
A is cis, B is trans
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Solution
The correct option is D A is cis, B is trans Birch reduction gives trans product and lindlar's catalyst gives cis. Hence correct option is (a).
Birch Reduction takes place in presence of Na/liq.NH3
Lindlar's catalyst is H2,Pd/C