The correct option is D 14th day
Ovulation is the second phase of the ovarian cycle in which a mature egg is released from the ovarian follicles into the oviduct. When the egg has nearly matured, levels of estradiol reach a threshold above, which this effect is reversed and estrogen stimulates the production of a large amount of LH. This process is known as the LH surge, starts around day 12 - 13 of the average cycle and may last 48 hours. Hence, option A is correct.