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Question


According to Freundlich isotherm, the above graph will be true when:

A
P=0
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B
P=1
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C
1n=0
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D
1n=
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Solution

The correct option is C 1n=0
Freundlich adsorption gives the variation in the quantity of gas adsorbed by a unit mass of solid adsorbent with the change in pressure of the system for a given temperature. The expression for the Freundlich isotherm can be represented by the following equation:
xn=kP1n

where n>1

Where x is the mass of the gas adsorbed, m is the mass of the adsorbent, P is the pressure and n is a constant which depends upon the nature of adsorbent and the gas at a given temperature.

Generally according to Freundhlich adsorption theory, at high pressure 1n value tends to 0 and hence the amount of adsorbed becomes independent of pressure.
So, above graph is valid if 1n=0 and high pressure.
So the answer is option (c).

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