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Question

According to langmuir adsorption isotherm:
For adsorption of a gas over solid surface, rate of adsorption is proportional to:

A
Fraction of surface available for adsorption.
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B
Pressure of gas
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C
Both (a) and (b)
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D
Fraction of surface covered on adsorbent.
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Solution

The correct option is C Both (a) and (b)
In Langmuir adsorption isotherm,
Θ : Fraction of surface covered on adsorbent
1Θ : Free surface are
P : Pressure of gas
By langmuir adsorption isotherm,
Rate of adsorption Fraction of surface available for adsorption
Rate of adsorption Pressure of gas

Rate of adsorption P(1Θ)
Rate of adsorption =ka P(1Θ)

Rate of dessorption Fraction of surface covered on adsorbent
Rate of desorption Θ
Rate of desorption =kd Θ
ka and kd are rate constants.

At equilibrium condition,
Rate of adsorption =Rate of desorption

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