According to langmuir adsorption isotherm:
For adsorption of a gas over solid surface, rate of adsorption is proportional to:
A
Fraction of surface available for adsorption.
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B
Pressure of gas
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C
Both (a) and (b)
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D
Fraction of surface covered on adsorbent.
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Solution
The correct option is C Both (a) and (b) In Langmuir adsorption isotherm, Θ : Fraction of surface covered on adsorbent 1−Θ : Free surface are P : Pressure of gas
By langmuir adsorption isotherm, Rate of adsorption ∝ Fraction of surface available for adsorption Rate of adsorption ∝ Pressure of gas ∴ Rate of adsorption ∝P(1−Θ) Rate of adsorption =kaP(1−Θ)
Rate of dessorption ∝ Fraction of surface covered on adsorbent Rate of desorption ∝Θ Rate of desorption =kdΘ ka and kd are rate constants.
At equilibrium condition, Rate of adsorption =Rate of desorption