According to the following equation, K2Cr2O7+4H2SO4→K2SO4+Cr2(SO4)3+4H2O+3[O] the equivalent mass of K2Cr2O7 is
A
mol.mass/3
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B
mol.mass/6
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C
mol.mass
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D
mol.mass/12
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Solution
The correct option is Cmol.mass/3 In the above reaction cromium changed its oxidation number from from +6 to +3 that is 3 electrons are gained. So equivalent weight=molecular weight/number of electrons gained. Therefore equivalent weight=molecular weight/3 Hence option A is correct.