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Question

Acetic acid and aq.NH3 are weak monobasic acid and weak monoacidic base respectively and Ka of acetic acid is equal to Kb of aq.NH3. Which of the following statements are incorrect?

A
The mixing of CH3COOH and NH3 in any proportion would result in neutral solution having pH=7 at 25C
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B
If aq.NH3 is exactly half neutralised by HCl, then pOH of resulting solution is equal to pKb
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C
If acetic acid is exactly half neutralised by NaOH then pH of resulting solution is equal to pKb
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D
If acetic acid is exactly neutralised by aq.NH3 then pH of resulting solution is equal to 1/2pKw
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Solution

The correct options are
C If acetic acid is exactly half neutralised by NaOH then pH of resulting solution is equal to pKb
D If acetic acid is exactly neutralised by aq.NH3 then pH of resulting solution is equal to 1/2pKw
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