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Question

Acetic acid dimerises in vapour phase at 437K as 2CH3COOH(g)(CH3COOH)2(g). A mass of 0.0519g of acetic acid was found to have 764.3mm pressure at 437K in a container of 21.45cm3. Calculate degree of dimerisation for acetic acid dimerisation.

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Solution

61%, and equilibrium constant (Kc) and (Kp) 2.3×103litremol1,64.1atm1

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