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Standard XII
Chemistry
Abnormal Colligative Properties
Acetic acid e...
Question
Acetic acid exists in a dimer state in benzene, due to __________.
A
condensation reaction
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B
hydrogen bonding
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C
presence of carbonyl group
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D
presence of
α
- hydrogen
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Solution
The correct option is
C
hydrogen bonding
In benzene solution, acetic acid forms dimer due to intramolecular hydrogen bonding.
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Similar questions
Q.
Acetic acid exists as dimer in benzene due to:
Q.
Acetic acid is a dimer in benzene due to:
Q.
The freezing point of
0.02
mol fraction of acetic acid in benzene is
277.4
K
. Acetic acid exists partly as a dimer. Calculate the equilibrium constant for dimerization. (approximately)
(Freezing point of
C
6
H
6
=
278.4
K
and
K
f
of
C
6
H
6
=
5
K
m
−
1
)
Q.
The freezing point of a solution of acetic acid (mole fraction =
0.02
) in benzene is
277.4
K
. Acetic acid exists partly as a dimer
2
A
⇌
A
2
.
Determine the equilibrium constant for dimerisation. Freezing point of benzene is
278.4
K
and
K
f
for benzene is
5
.
Q.
The freezing point of
0.02
mole fraction of acetic acid in benzene is
277.4
K. Acetic acid exists partly as dimer. Calculate the equilibrium constant for dimerisation. Freezing point of benzene is
278.4
K and heat of fusion of benzene is
10.042
kJ mol
−
1
.
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