Acetic acid on warming with $C l_{2}$ in the presence of red P gives ___________.

C H_{3} C O C l

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C H_{3} C H_{2} C l

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C l_{3} C C O O H

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C H_{3} C O O C l

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Solution

The correct option is C $C l_{3} C C O O H$
$C H_{3} C O O H + C l_{2} r e d P - -- \to C H_{2} C l C O O H + H C l M o n o C h l o r o a c e t i c a c i d$
$C H_{2} C l C O O H + C l_{2} r e d P - -- \to C H C l_{2} C O O H + H C l D i c h l o r o a c e t i c a c i d$
$C H C l_{2} C O O H + C l_{2} r e d P - -- \to C C l_{3} C O O H + H C l T r i c h l o r o a c e t i c a c i d$

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