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Question

Acetone and acetaldehyde can be distinguished by using_______.

A
Grignard reagent
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B
NaHSO3
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C
ammoniacal AgNO3
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D
PCl5
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Solution

The correct option is C ammoniacal AgNO3
Tollens' reagent is silver ammonia complex or ammoniacal AgNO3 solution.

It oxidizes acetaldehyde to acetic acid. Silver ions are reduced to silver metal. This gives silver mirror.

Such silver mirror is not obtained with acetone.

Hence, Tollens' reagent is used to distinguish acetaldehyde and acetone.

Option C is correct.

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