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Question

Acetophenone can be obtained by the reaction of PhMgBr and :

A
Ethane nitrile
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B
Ethanamide
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C
Ethanoyl chloride
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D
Methanamide
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Solution

The correct options are
A Ethane nitrile
B Ethanamide
Acetophenone can be obtained by the reaction of phenyl magnesium bromide (PhMgBr - a Grignard reagent) and either (A) Ethane nitrile or (B) Ethanamide.
On the other hand, the reaction of PhMgBr with Ethanoyl chloride will give a tertiary alcohol and the reaction of PhMgBr with Methanamide will give benzaldehyde.
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