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Formation of Hemiacetals

Acetophenone ...

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Acetophenone when reacted with a base,C2HONa, yields a stable compound which has thestructure?\lbrack AIPMT (Prelims)-2008\rbrack

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Q. A compound of molecular formula

C_{8} H_{8} O_{2}

reacts with acetophenone to form a single cross-aldol product in the presence of base. The same compound on reaction with conc. NaOH forms benzyl alcohol as one of the products. The structure of the compound is :

Q. Ethyl chloride reacts with sodium ethoxide to form a compound

A

. Which of the following reacted to yields

A

?

Q. Which compounds are formed when an acid reacts with a base?

Q. A compound of molecular formula

C_{8} H_{8} O_{2}

reacts with acetophenone to form a single cross-aldol product in the presence of a base. The same compound on reaction with conc.

N a O H

forms benzyl alcohol as one of the products. What is the structure of the compound?

Q. An organic compound 'A',

C_{8} H_{6}

on reacting with dil

H_{2} S O_{4}

H g S O_{4}

gives a compound 'B' which can also be obtained from reaction of benzene with acid chloride in the presence of anh.

A l C l_{3}

. Compound 'B' when reacted with iodine and aq. NaOH yields 'C' and a yellow compound 'D' . Identify A to D with proper justification.

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Formation of Hemiacetals

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