Activation energy of forward and backward process of the reaction are 60kJ and 40kJmol−1 respectively. Which of the following are true for the reaction?
A
It is an endothermic reaction.
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B
It is an exothermic reaction.
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C
Heat of reaction is +20kJmol−1.
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D
Threshold energy of reaction can be 100kJmol−1.
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Solution
The correct options are A It is an endothermic reaction. C Heat of reaction is +20kJmol−1. D Threshold energy of reaction can be 100kJmol−1. Eaf=60kJ/mol,Eab=40kJ/mol
ΔH=Eaf−Eab=+20kJ/mol
ΔH is positive, reaction is endothermic.
Threshold energy is the energy that a molecule must have to make effective collision.
threshold energy is greater than activation energy.
For given reaction, threshold energy can be 100 kJ/mol.