The correct option is A (n+1)s
After np-orbitals are filled, the next orbital filled will be (n+1)s.
According to Aufbau principle, orbitals are filled in order of increasing value of (n+l).
If two orbitals have same value of (n+l), then the orbital with lower value of n will be filled first.
For np orbital, (n+l)=(n+1)
For (n+1)s orbital, (n+l)=(n+1+0)=(n+1)
For (n+2)p orbital, (n+l)=(n+2+1)=(n+3)
For (n+1)d orbital, (n+l)=(n+1+2)=(n+3)
For (n+2)s orbital, (n+l)=(n+2+0)=(n+2)