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Question

Ag2S+NaCN+ZnAg
This method of extraction of Ag by complex formation and then its displacement is called_______.

A
Parke's method
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B
Mac Arthur- Forrest method
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C
Serpeck method
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D
Hall's method
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Solution

The correct option is A Mac Arthur- Forrest method
Cyanide process is used for extraction of Ag which is also called Mc-Arthur forest process.Reactions occurs in extraction of silver -

Ag2S+4NaCN2Na[Ag(CN)2]+Na2S (reversible reaction)

4Na2S+5O2+H2O2Na2SO4+4NaOH+2S

and 2Na[Ag(CN)2]+ZnNa2[Zn(CN)4]+2Ag

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Cyanide or MacArthur Forrest Process
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