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Question

AgCI dissolved in KCN, NH3 and Na2S2O3, solutions, the complex ions produced respectively are

A
[Ag(CN)2]3, [Ag(NH3)2]1 and [Ag(S2O3)2]+
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B
[Ag(CN)2]1, [Ag(NH3)2]+ and [Ag(S2O3)2]3
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C
[Ag(CN)2]3, [Ag(NH3)4]+ and [Ag2(S2O3)2]2
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D
[Ag(CN)2]+, [Ag(NH3)4]+ and [Ag2(S2O3)2]3
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Solution

The correct option is B [Ag(CN)2]1, [Ag(NH3)2]+ and [Ag(S2O3)2]3
AgCl+2KCNK[Ag(CN)2]+KCl
AgCl+2NH3[Ag(NH3)2]Cl
AgCl+2Na2S2O3Na3[Ag(S2O3)2]+NaCl

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