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Question

AgNO3 (aq) was added to an aqueous KCl solution gradually and the conductivity of the solution was measured. The plot of conductance (Λ) versus the volume of AgNO3 is :

28691.PNG

A
(P)
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B
(Q)
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C
(R)
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D
(S)
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Solution

The correct option is C (S)
AgNO3+KCl(aq)AgCl(s)+KNO3(aq)

Initially, to the solution of KCl, solution of AgNO3 added, AgCl(s) is formed.

Hence, the conductivity of the solution is almost compensated (or slightly increase) by the formation of KNO3. After end point, conductivity increases more rapidly because of the addition of excess AgNO3 solution.

Hence, option D is correct.

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