The correct option is D Ag2S
Reaction:
2AgNO3+Na2S2O3→Ag2S2O3+2NaNO3
If hypo is taken in a limited amount, then this happens. The Ag thiosulphate thus formed goes through a change of colour (termed as 'play of colour').
Ag2S2O3(white)→yellow→orange→brown→black(Ag2S ppt.)