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Question

AgNO3 gives white ppt. with hypo changing to black after some-time. Black ppt is of :

A
Ag2S2O3
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B
Ag2SO4
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C
Ag2S4O6
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D
Ag2S
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Solution

The correct option is D Ag2S
Reaction:
2AgNO3+Na2S2O3Ag2S2O3+2NaNO3
If hypo is taken in a limited amount, then this happens. The Ag thiosulphate thus formed goes through a change of colour (termed as 'play of colour').
Ag2S2O3(white)yelloworangebrownblack(Ag2S ppt.)

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