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Question

Al3+(aq.)+3eAl(s);E=1.66 V
Cu2+(aq.)+2eCu(s);E=+0.34 V

What voltage is produced under standard conditions by combining the half reactions with these standard electrode potentials?

A
1.32 V
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B
2.00 V
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C
2.30 V
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D
4.34 V
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Solution

The correct option is B 2.00 V
The cell will be:
Al(s)|Al3+(aq.)||Cu2+(aq.)|Cu(s)

Ecell=ECathodeEAnode

=ECu2+/CuEAl3+/Al

=+0.34(1.66)=+2.00 V.

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