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Question

Alkane can be iodinated in the presence of:

A
HI
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B
I2 and P
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C
HIO3
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D
PI3
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Solution

The correct option is C HIO3
Iodination of an alkane is carried out in the presence of oxidizing agent because one of the products of this reaction is hydrogen iodide and this is a strong reducing agent and converts alkyl iodide back to an alkane.

Therefore to counter this difficulty, the iodination of alkanes are carried out in the presence of a strong oxidizing agent like iodic acid (HIO3) which oxidizes the hydrogen iodide formed.

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