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Reactions of Aryl Amines (Diazo Salts)

Alkyl groups ...

Question

Alkyl groups directly attached to the positively charged carbon stabilize the carbocations due to:

A

Inductive and hyperconjugation effect

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B

Isomerism

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C

Resonance effect

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D

Chirality

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Solution

The correct option is A
Inductive and hyperconjugation effect

Alkyl groups directly attached to the positively charged carbon stabilize the carbocations due to inductive and hyperconjugation effect.

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A carbocation is a group of atoms with a positively charged carbon atom having six electrons in the valence shell after sharing. Carbocations are formed in the heterolysis of a bond and are planar species. Stability of carbocation is determined by inductive effect, hyperconjugation and resonance effect. Greater the number of contributing structures more is the stability of a Carbocation. Electron releasing groups (+I effect) increases the stability of a carbocation whereas the electron withdrawing groups (I effect) have an opposite effect.

Which of the following is most stable carbocation?

Q. Answer the question on the basis of information given below:
"Stability of carbocation's depends upon the electron releasing inductive effect of groups adjacent to positively charged carbon atom involvement of neighboring groups in hyperconjugation and resonance."
Which of the following ions is more stable? Use resonance to explain your answer.

The stability of (CH₃)₂C=CH₂ is more than that of CH₃CH₂CH=CH₂ due to

The stability of $M e_{2} C = C H_{2}$ is more than that of $M e C H_{2} C H = C H_{2}$ due to:

Q. Which of the following is the correct order of the dominating power of the given effects on the stability of intermediates?
I. Resonance effect II. Hyperconjugation
III. Inductive effect IV. Aromaticity

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Reactions of Aryl Amines (Diazo Salts)

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