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Question

Alkyl iodides can be prepared by:-

A
RCH2COOAg+I2CCl4ΔRCH2I
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B
RCH2Cl+NaIacetoneΔRCH2I+NaCl
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C
ROH+HIRI+H2O
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D
CH4+I2CH3I
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Solution

The correct options are
B ROH+HIRI+H2O
C RCH2Cl+NaIacetoneΔRCH2I+NaCl
Alkyl halides are prepared by following reactions:
Finkelstein reaction or halogen exchange reaction:
RCH2Cl+NaIacetoneΔRCH2I+NaCl

ROH+HIRI+H2O
Requires presence of sulphuric acid.
The reaction CH4+I2CH3I is reversible and must be carried out in presence of oxidizing agents such as HIO3,HNO3 or HIO4

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