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Byju's Answer
Standard XII
Chemistry
Reaction with Metals
All halides o...
Question
All halides of
C
u
(
I
I
)
are known except the iodide because:
A
C
u
2
+
oxidises
I
−
to
I
2
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B
copper (II) iodine undergoes disproportionation
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C
I
2
is a good oxidizing agent
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D
iodine atom has electron affinity
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Solution
The correct option is
D
C
u
2
+
oxidises
I
−
to
I
2
The reason is
C
u
2
+
oxidizes iodide to iodine.Hence all halides of
C
u
(
I
I
)
are known except the iodide.
Hence option A is correct answer.
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0
Similar questions
Q.
Assertion :Copper(II) iodide is not known. Reason:
C
u
2
+
oxidises
I
−
to
I
2
.
Q.
Consider the disproportionation of Iodine to iodide and iodate ions. Using Oxidation method calculate the ratio of iodate and iodide ions formed in alkaline medium :
I
2
→
I
O
−
3
+
I
−
Q.
Assertion :Copper (II) iodide is unstable even at ordinary temperature. Reason: The
C
u
2
+
ion with a 17-electron outer-shell and a comparatively small radius (0.08 nm) has a strong polarising power, while the iodide ion with a larger radius (r = 0.22 nm) has a high polarisability. Hence, the polarisation of the
I
−
by the
C
u
2
+
leads to the complete transition of an electron from the anion to the cation. The
C
u
2
+
ion is thus reduced to
C
u
ion and
I
−
is oxidised to free iodine. The compound
C
u
I
2
therefore, does not exist.
2
C
u
I
2
⟶
2
C
u
I
+
I
2
2
I
−
⟶
I
2
+
2
e
−
C
u
2
+
+
2
e
−
⟶
C
u
Q.
During the disproportionation of Iodine to iodide and iodate ions, the ratio of iodate and iodide ions formed in alkaline medium is:
I
2
→
I
O
−
3
+
I
−
Q.
Consider the disproportionation of Iodine to iodide and iodate ions. Using Oxidation method calculate the ratio of iodate and iodide ions formed in alkaline medium :
I
2
→
I
O
−
3
+
I
−
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