The correct option is B 74
Alphabets present in the word DEMAND are D,E,M,A,N,D
Dictionary order of these letters is A,D,D,E,M,N
Words starting with A:5!2!=60
Words starting with A where two D′s are together =4!=24
∴ Words starting with A, without two D′s adjacent to each other =60−24=36
Next we have words starting with D.
Within this, we have words starting with DA (DA _ _ _ _): 4! words =24 words
Then words starting with DE
Within this, words starting with DEA (DEA _ _ _)⇒3!=6 words
Then starting with DED (DED _ _ _)⇒3!=6 words
Then starting with DEM
⇒ First word is DEMADN
⇒ Second word is DEMAND
∴ Rank of the word DEMAND=36+24+6+6+2=74