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Question

All the released energy from the reaction XY,ΔrG0=193 kJ mol1 is used for oxidizing M+M3++2e, E0=0.25 V
Under standard conditions, the number of moles of M+ oxidized when one mole of X is converted to Y is [F=96500 C mol1]

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Solution

M+M3++2e
ΔG0=nFE0 For 1 mole of M+
ΔG0=2×96500×(0.25) J
=+48250 J/mole
=48.25 kJ/mole
Energy released by conversion of 1 mole of
XY ΔG=193 kJ
Hence, moles of M+ converted
19348.25=4

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