Aluminimum chloride exists as dimer, $A l_{2} C l_{6}$ , in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives :

A l^{3 +} + 3 C l

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[A l (H_{2} O)_{6}]^{3 +} + 6 C l^{-}

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[A l (O H)_{6}]^{3 +} + 3 H C l

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A l_{2} O_{3} + 6 H C l

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Solution

The correct option is B $[A l (H_{2} O)_{6}]^{3 +} + 6 C l^{-}$
Aluminimum chloride exists as dimer, $A l_{2} C l_{6}$ , in solid state as well as in solution of non-polar solvents such as benzene. When dissolved in water, it gives $[A l (H_{2} O)_{6}]^{3 +} + 3 C l^{-}$ .
The balanced chemical reaction is
$A l_{2} C l_{6} + 12 H_{2} O \to 2 [A l (H_{2} O)_{6}]^{3 +} + 6 C l^{-}$

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