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Question

Aluminium (III) chloride forms a dimer through

A
Chlorine bridging
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B
hydrogen bond
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C
Aluminium bridging
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D
(a) and (c) above.
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Solution

The correct option is A Chlorine bridging
AlCl3 can form dimer through halogen bridging and exists as Al2Cl6 because it has vacant d-orbitals which can accommodate electron from chlorine atom.


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