The correct option is D Fluorspar
Cryolite; Na3AlF6, sodium hexafluoroaluminate.
Mica: KAl3Si3O10(OH)2 Basic potassium aluminum silicate
Feldspars KAlSi3O8NaAlSi3O8CaAl2Si2O8.
fluorspar: CaF2,calcium fluoride.
So only in fluorspar there is no Al present.
Hence option D is correct.