Aluminium oxide may be electrolysed at 1000oC to furnish aluminium metal. The cathode reaction is Al3++3e−→Al. To prepare 5.12kg of aluminium metal by this method would require:
A
5.49×101C of electricity
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B
5.49×104C of electricity
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C
1.83×107C of electricity
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D
5.49×107C of electricity
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Solution
The correct option is C5.49×107C of electricity Mass of Al deposited =5.12kg=5.12×103gm Mass of Al deposited =Q(C)96500Cmole−× mole ratio× molar mass . Substituting the mass of Al deposited in the above equation: