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Haber Bosch Process

AMINES: Why i...

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AMINES: Why in case of alkyl amines reaction with NaNO2 HCl gives - OH instead of NH2 but in case of aryl amines we get N2+Cl-?

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Q. Primary amine on treating with NaNO₂ and HCl produce:

Q. Which of the following amines will give primary alcohol with

N a N O_{2} / C o n c . H C l :

(a) C H_{3} - C H_{2} - C | C H_{3} - N H_{2}

(b) C H_{3} - C H_{3} | C | C H_{3} - N H_{2}

(c) C H_{3} - C | C H_{3} - C H_{2} - C H_{2} - N H_{2}

(d) A l l o f t h e s e

Q. Assertion :Gabriel phthalimide rection can be used to prepare aryl amines Reason: Aryl halides have same reactivity as alkyl halids towards nucleophilic substitution reactions.

Q. Which of the following alkene cannot be prepared by de-amination of

n - B u - N H_{2} (n - B u t y l)

N a N O_{2} / H C l

?

Q. Primary amines on heating with

C H {C l}_{3}, K O H

N a O H

form alkyl isocyanides. This reaction is called:

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