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Question

Ammonia gas at 15 atm is introduced in a rigid vessel at 300 K. At equilibrium the total pressure of the vessel is found to be 40.11 atm at 300 C. The degree of dissociation of NH3 will be :

A
0.6
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B
0.4
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C
unpredictable
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D
none of these
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Solution

The correct option is B 0.4
2NH3N2+3H2
T=300K 15 atm
T=573K 15300(573)atm
15300(573)[1+α)=40.11α=0.4

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