The correct option is B sodium nitrite
In the laboratory, a mixture of ammonium chloride and sodium nitrite is heated to prepare nitrogen gas. This on heating produce ammonium nitrite. The reaction involved is:
NH4Cl(aq)+NaNO2(aq)→NH4NO2(aq)+NaCl(aq)
Ammonium nitrite is highly unstable and it decomposes to produce nitrogen. The reaction involved is:
NH4NO2(aq)→N2(g)+2H2O(l)