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Question

Ammonium hydroxide solution can be used to distinguish between zinc ion and calcium ion.


A

True

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B

False

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Solution

The correct option is A

True


When ammonium hydroxide is added to a salt solution of zinc, such as zinc nitrate solution, a white precipitate is formed. The white precipitate dissolves when excess ammonium hydroxide is added.

Zn(NO3)2+NH4OHZn(OH)2(ppt)+NH4NO3

Zn(OH)2+NH4OH(excess)[Zn(NH3)4]SO4+H2O

But when ammonium hydroxide is added to a salt solution of the calcium, such as calcium nitrate solution, there is no visible reaction.

Ca(NO3)2+NH4OHNo precipitate of Ca(OH)2 is formed


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