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Question

Among ( A or B ) which follows a SN1 mechanism?

A. (CH3)3CCl or
B. CH3Cl

[Give your answer in terms of A or B]

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Solution

Methyl chloride will react faster than tert butyl chloride towards bimolecular nucleophilic substitution reaction with hydroxide ion.

In general, primary alkyl halides react via a SN2 mechanism whereas tertiary alkyl halides react via SN1 mechanism. Since the compounds ( A ) are a tertiary alkyl halide, so it can follow a SN1 mechanism.

So, the correct answer is ( A )

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