Among the electrolytes Na2SO4,CaCl2,Al2(SO4)3 and NH4Cl, the most effective coagulating agent for Sb2S3 sol is
Al2(SO4)3
Sb2S3 is a negative (anionic) sol. According to Hardy Schulze rule, greater the valency of cationic coagulating agent, higher its coagulating power. Therefore, Al2(SO4)3 will be the most effective coagulating agent in the present case.