Tendency of atoms of an element to lose electrons and form positive ion is known as electropositivity.
A more electropositive element has more metallic character.
On going along a group from top to bottom, the metallic character of elements increases.
Electropositive and Metallic character: Increases down a group
Li < Na < K < Rb < Cs
So among the first four alkali metals, Rb is more electropsitive.