Among the following complex ions, which is diamagnetic in nature is

[C o F_{6}]^{3 -}

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[N i C l_{4}]^{2 -}

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[N i (C N)_{4}]^{2 -}

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[C u C l_{4}]^{2 -}

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Solution

The correct option is C $[N i (C N)_{4}]^{2 -}$
In $[N i (C N)_{4}]^{2 -}$ , Ni has $d s p^{2}$ hybridisation where, $C N^{-}$ is a strong ligand. Hence, all electrons in 3d are paired.

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d p^{2}

^{'} [N i (C N)_{4}]^{2 -}

[N i C l_{4}]^{2 -}

{[N i {(C N)}_{4}]}_{4}^{2 -}

{[N i C l_{4}]}_{4}^{2 -}

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