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Ionic Compounds and Radius Ratios

Among the fol...

Question

Among the following complexes
$[{Ru(bipyridyl)}_{3})]^{2 +}, [C r (E D T A)]^{2 +}, trans- [C r C l_{2} (o x)_{2}]^{3 -}$ and $cis- [C r C l_{2} (o x)_{2}]^{3 -}$ , the total number of complexes that shows chirality are:

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Solution

$[R u (b p y)_{3})]^{2 +}, [C r (E D T A)]^{2 +}$ and $c i s - [C r C l_{2} (o x)_{2}]^{3 -}$ are optically active.

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[C r (E D T A)]^{-}

[R u (e n)_{3}]^{2 +}

[P t (g l y)_{2} C l_{2}]^{- 2}

C i s - [C r (C l)_{2} (o x)_{2}]^{3 -}

[P t (e n) (N H_{3})_{2} (p y)_{2}]^{4 +}

| p + q |^{2}

p = total number of optically active complexes

q = total number of optically inactive complexes

(i) [C o (N H_{3})_{4} (H_{2} O) C l]^{2 +} (i i) [P t (N H_{3})_{2} C l_{2}] (i i i) [C o C l_{2} (e n)_{2}]^{+} (i v) [C r (H_{2} O)_{5} C l] C l_{2} (v) [F e (N H_{3})_{2} (C N)_{4}]^{-} (v i) [C r C l_{2} (o x)_{2}]^{3 -} (v i i) K [C o (H_{2} O)_{2} (o x)_{2}] (v i i i) [C o (N H_{3})_{2} C l_{2} (e n)]^{+} (i x) [C o (e n)_{3}] C l_{3}

cis-trans

[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

[C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} C l_{2}]^{+}, [C r C l_{2} (C_{2} O_{4})_{2}]^{3 -}, [F e (H_{2} O)_{4} (O H)_{2}]^{+}, [F e (N H_{3})_{2} (C N)_{4}]^{-}, [C o (N H_{2} - C H_{2} - C H_{2} - N H_{2})_{2} (N H_{3}) C l]^{2 +}

[C o (N H_{3})_{4} (H_{2} O) C l]^{2 +}

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