The correct option is C H2CO3
a) In BF3, B is sp2 hybridised, has trigonal planar geometry and is symmetric. So, it is not a polar molecule.
b) In HClO4, Cl is sp3 hybridised.
c) In H2CO3, C is sp2 hybridised and the C=O dipole is not balanced by C−O dipoles, thus it is also a polar molecule.
d) In SiF4, Si is sp3 hybridised.